Novel N,N-diacetyloximo-1,3-phenylenediamine copper(II) complexes

  • El-Tabl, Abdou Saad

  • Chemistry Department, Faculty of Science, Menofia University, Shebin El-Kom, Egypt

Transition Metal Chemistry 22(4):p 400-405, 1997.

Summary

N,N-Diacetyloximo-1,3-phenylenediamine (H2L) reacts with copper(II) ions to yield octahedral complexes, which have been characterized by elemental analysis, i.r. and u.v.-vis. spectroscopy, magnetic moments, conductance and e.s.r. measurements. The molar conductance values of the complexes in DMF are commensurate with their non-electrolytic nature, the g∥ - values show considerable covalent bonding with a dx2-y2 ground state.

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